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NICKEL CARBONYL | ICSC: 0064 |
Nickel tetracarbonyl C4NiO4/Ni(CO)4 Molecular mass: 170.7 ![]() RTECS # QR6300000 ICSC # 0064 UN # 1259 EC # 028-001-00-1 |
TYPES OF HAZARD/ EXPOSURE |
ACUTE HAZARDS/ SYMPTOMS |
PREVENTION |
FIRST AID/ FIRE FIGHTING |
FIRE |
Highly flammable.
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NO open flames, NO sparks, and NO smoking.
NO contact with oxidants.
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Powder, water spray, foam, carbon dioxide.
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EXPLOSION |
Vapour/air mixtures are explosive.
Risk of fire and explosion upon heating above 60░C.
Liquid and vapour flash in direct sunlight.
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Closed system, ventilation, explosion-proof electrical equipment and lighting.
Do NOT use compressed air for filling, discharging, or handling.
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In case of fire: keep drums, etc., cool by spraying with water.
Combat fire from a sheltered position.
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EXPOSURE |
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AVOID ALL CONTACT!
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IN ALL CASES CONSULT A DOCTOR!
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Abdominal pain.
Blue skin.
Cough.
Dizziness.
Headache.
Nausea.
Shortness of breath.
Vomiting.
Symptoms may be delayed (see Notes).
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Closed system and ventilation.
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Fresh air, rest.
Half-upright position.
Artificial respiration if indicated.
Refer for medical attention.
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MAY BE ABSORBED!
Redness.
Pain.
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Protective gloves.
Protective clothing.
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Remove contaminated clothes.
Rinse and then wash skin with water and soap.
Refer for medical attention.
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Redness.
Pain.
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Face shield
or eye protection in combination with breathing protection.
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First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then take to a doctor.
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Abdominal pain.
Headache.
Nausea.
Vomiting
(further see Inhalation).
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Do not eat, drink, or smoke during work.
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Rinse mouth.
Induce vomiting (ONLY IN CONSCIOUS PERSONS!).
Refer for medical attention.
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SPILLAGE DISPOSAL | STORAGE | PACKAGING & LABELLING | ||
Evacuate danger area!
Consult an expert!
Collect leaking and spilled liquid in sealable containers as far as possible.
Absorb remaining liquid in sand or inert absorbent and remove to safe place.
Do NOT wash away into sewer
(extra personal protection: complete protective clothing including self-contained breathing apparatus).
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Fireproof.
Separated from
strong oxidants,
strong acids,
food and feedstuffs.
Cool.
Keep in the dark.
Keep under inert gas.
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Airtight.
Do not transport with food and feedstuffs.
F symbol T+ symbol R: 61-11-26-40 S: 53-45 Note: E UN Hazard Class: 6.1 UN Subsidiary Risks: 3 UN Packing Group: I Severe marine pollutant. |
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SEE IMPORTANT INFORMATION ON BACK | ||||
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NICKEL CARBONYL | ICSC: 0064 |
I M P O R T A N T D A T A |
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PHYSICAL PROPERTIES |
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ENVIRONMENTAL DATA |
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N O T E S | ||||
Depending on the degree of exposure, periodic medical examination is indicated.
The symptoms of lung oedema often do not become manifest until a few hours have passed and they are aggravated by physical effort. Rest and medical observation are therefore essential.
Immediate administration of an appropriate spray, by a doctor or a person authorized by him/her, should be considered.
The symptoms of asthma often do not become manifest until a few hours have passed and they are aggravated by physical effort. Rest and medical observation are therefore essential.
Anyone who has shown symptoms of asthma due to this substance should avoid all further contact with this substance.
The odour warning when the exposure limit value is exceeded is insufficient.
Rinse contaminated clothes (fire hazard) with plenty of water.
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ADDITIONAL INFORMATION | |||||
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